Radical Copolymerization

Block and Graft Copolymerization by Controlled/Living Radical Polymerization Methods

Supporting Information for Interception Copper-based Carbene Radical with α-Carbonyl Diazomethane Radical: C1/C1N2 Copolymerization

Denture base polymers, poly methyl methacrylate improved using free radical copolymerization

Poly methyl methacrylate (PMMA) is the most common material used in Prosthodontics. Several studies indicate a breakdown of the number of very high resin bases after 2 to 3 years to avoid breaking bass and several attempts have been made, such as altering the chemical structure of resin by adding causes cross linking or copolymerization. The innovative method for improving the physical properti...

Sequence-regulated vinyl copolymers with acid and base monomer units via atom transfer radical addition and alternating radical copolymerization†

Mainand side-chain sequence-regulated vinyl copolymers with acid and base monomer units were prepared using atom transfer radical addition (ATRA) and alternating radical copolymerization. A series of maleimide-ended sequence-regulated “oligomonomers” were prepared by ATRA of t-butyl acrylate (tBA: Ap) (i.e., a protected acrylic acid (A)) or an amine-functionalized acrylate, (2-(dimethylamino)et...

Free radical crosslinking copolymerization. Gelation behavior of macromonomeric azoinitiators versus macrocrosslinkers

In order to evaluate the gelation behavior of macromonomeric azoinitiators (MIMs), the free radical polymerization of MIM and macrocrosslinkers (MCRs) have been compared. MIMs were synthesized by the reaction between 4,49-dicyano-4,49-azovaleryl chloride and poly(ethylene glycol)s PEG-400, -1000, -1500, -2000 and 4-vinylbenzyl chloride. MCRs were obtained by vinylation of both hydroxyl ends of ...